Backlit displays including organic light-emissive material

ABSTRACT

A display device comprising: a light switching unit comprising an array of pixels each operable to vary the transmission of light therethrough; and a backlight comprising a first series of regions of organic light-emissive material having a first emission colour and a second series of regions of organic light-emissive material having a second emission colour, each region of organic material being located so as to lie behind a plurality of pixels of the array in the viewing direction for backlighting those pixels; and at least one of the regions of organic light-emissive material being formed by a process of ink-jet deposition.

RELATED APPLICATIONS

This application is a continuation of U.S. Ser. No. 11/434,290, filedMay 15, 2006, pending, which is a continuation of U.S. Ser. No.09/719,955 filed Mar. 15, 2001, which issued as U.S. Pat. No. 7,116,308on Oct. 3, 2006, which is a national stage of PCT/GB99/01918 filed Jun.16, 1999, which claims priority to GB 9813326.7 filed Jun. 19, 1998, thecontents of which are all incorporated herein in their entirety.

FIELD OF THE INVENTION

This invention relates to display devices, especially backlit displaydevices, and backlights for displays. The backlighting is suitablyprovided by means of organic light-emissive material.

BACKGROUND OF THE INVENTION

Light-emissive organic materials are described in PCT/W090/13148 andU.S. Pat. No. 4,539,507, the contents of both of which are incorporatedherein by reference. The basic structure of these devices is alight-emissive organic layer, for instance a film of apoly(p-phenylenevinylene (“PPV”), sandwiched between two electrodes. Oneof the electrodes (the cathode) injects negative charge carriers(electrons) and the other electrode (the anode) injects positive chargecarriers (holes). The electrons and holes combine in the organic layergenerating photons. In PCT/W090/13148 the organic light-emissivematerial is a polymer. In U.S. Pat. No. 4,539,507 the organiclight-emissive material is of the class known as small moleculematerials, such as (8-hydroxyquinolino)aluminium (“Alq3”). In apractical device, one of the electrodes is typically transparent, toallow the photons to escape the device.

FIG. 1 shows the typical cross-sectional structure of an organiclight-emissive device (“OLED”). The OLED is typically fabricated on aglass or plastic substrate 1 coated with a transparent first electrode 2such as indium-tin-oxide (“ITO”). Such coated substrates arecommercially available. This ITO-coated substrate is coated with atleast a layer of a thin film of an electroluminescent organic material 3and a final layer forming a second electrode 4 which is typically ametal or alloy. Other layers can be added to the device, for example toimprove charge transport between the electrodes and theelectroluminescent material.

Organic light-emissive materials have great potential for use in variousdisplay applications. One such application is as a backlight fortransmissive or transflective liquid crystal displays. In a liquidcrystal display there is typically a planar liquid crystal cell whichhas active regions where the optical properties of the liquid crystalmaterial can be altered by the application of an electric field to varythe transmission of light through the regions. In a transmissive liquidcrystal display there is a light source behind the liquid crystal panel;and light from the source shines to a viewer through those of theregions through which light can be transmitted. In a transflectiveliquid crystal display the light source is supplemented by a reflectivemirror, also behind the liquid crystal panel, which can return incidentlight towards the viewer.

The shape and layout of the active liquid crystal regions is generallydefined by the pattern of electrodes in the LCD. Some patterns arespecific to alpha-numeric or special character formats. An alternativeis a general dot matrix display pattern, in which the active regions areusually arranged to provide an array of pixels. The pixels are normallyarranged in an orthogonal grid layout, with the pixels arranged inmutually perpendicular linear rows and columns, but other layouts suchas non-orthogonal grids are possible. The LCD pixels can be controlledby a conventional display controller.

FIG. 2 shows a schematic plan view of the basic structure of apassive-matrix LCD. There are orthogonal row 10 and column 11 lines of atransparent conductor such as ITO. These form the electrodes. The rowand column lines are separated in the plane of FIG. 2 by the liquidcrystal layer itself. (For simplicity other LCD components such aspolarisers, alignment layers, the liquid crystal layer and colourfilters are omitted from FIG. 2). The areas where row and column linesoverlap define the active regions (pixels) of the device (e.g. at 13),which can be addressed by applying a voltage between the relevant rowand column lines. Because the column lines run across the row lines itis not possible to individually address all the pixels at the same time.Instead, the pixels are addressed with a row-by-row scan. An alternativedrive arrangement for an LCD is the active-matrix arrangement, in whicheach pixel has individual control circuitry, which can conveniently bein the form of thin-film transistors (TFTs), to allow more continuousdriving of the pixels.

To manufacture a multi-colour display using an LCD panel it is known toprovide backlights which are selectively operated to emit coloured lightthrough pixels of the LCD panel. The operation of the backlights and theLCD panel can, if necessary, be synchronised so that the LCD pixelsallow light to pass through a pixel only when the appropriate backlightcolour is being emitted. For example, WO 91/10223 describes a backlitLCD formed by placing a single LCD panel, which provides a matrix ofpixels, over a bank of red, green and blue fluorescent lamps. The aim ofthis arrangement is to improve efficiency by avoiding the need forcolour filters to provide the coloured light. WO 93/13514 describes acolour fluorescent backlight for an LCD in which a backlight is providedby a plurality of phosphorescent strips capable of emitting red, greenand blue light located in a vacuum chamber. PCT/GB96/00924 describes theuse of a light modulator comprising a passive matrix LCD and anelectroluminescent LED. The light source is addressable to emit lightfrom selected regions, each region overlapping at least a plurality ofrows of the light modulator, with the aim of reducing crosstalk in thedisplay.

SUMMARY OF THE INVENTION

There is a need for a simplified and less expensive system to providecolour backlighting for LCDs etc., especially one in which thebacklighting can be finely distributed, to cope with small LCD pixels,and precisely positioned.

According to one aspect of the present invention there is provided adisplay device comprising: a light switching unit comprising an array ofpixels each operable to vary the transmission of light therethrough; anda backlight comprising a first series of regions of organiclight-emissive material having a first emission colour and a secondseries of regions of organic light-emissive material having a secondemission colour, each region of organic material being located so as tolie behind a plurality of pixels of the array in the viewing directionfor backlighting those pixels; and at least one of the regions oforganic light-emissive material being formed by a process of ink-jetdeposition.

According to a second aspect of the present invention there is provideda method for forming a light-emissive unit of a display device, thedisplay device having a light switching unit comprising an array ofpixels each operable to vary the transmission of light therethrough, themethod comprising the steps of: forming a series of grooves on asubstrate; depositing by means of ink-jetting in some of the grooves afirst organic light-emissive material having a first emission colour;depositing by means of ink-jetting in others of the grooves a secondorganic light-emissive material having a second emission colour; andlocating the grooves such that the light-emissive material in eachgroove lies behind a respective plurality of pixels of the array in theviewing direction for backlighting those pixels.

Preferably each region of organic light-emissive material is formed by aprocess of ink-jet deposition. This suitably allows for efficient, fineand accurate definition of those regions.

The backlight may comprise a third series of regions of organiclight-emissive material having a third emission colour; and may comprisemore such regions, giving four or more emission colours. Each region oforganic light-emissive material having one emission colour is suitablyspaced from the next such region by at least regions of organiclight-emissive material having both of the other emission colours. Forexample, the materials may alternate across the plane of the device. Onepreferred option is for the materials to be red, green and bluelight-emissive. The regions of organic light-emissive material arepreferably linear regions, but could be curved, irregularly shaped orhave other forms. Adjacent regions preferably run side-by-side, so thatwhere the regions are linear they are preferably parallel. Preferably asingle one of the regions of light-emissive material lies behind eachpixel.

It is preferred that where one of the regions of light-emissive materialis formed by means of ink-jet deposition it is formed by means ofink-jet deposition of material into a groove. That groove (an inparticular its walls) may be defined by regions of electricallyinsulating material.

The backlight preferably comprises electrodes located on either side ofthe light-emissive material. At least one of the electrodes ispreferably light transmissive, and that electrode preferably liesbetween the emissive material and the pixels. Where the device comprisesthe said insulating material defining grooves it is preferred that partsof at least one of the electrodes overlap parts of that insulatingmaterial and lie in front of those parts of the insulating material inthe viewing direction. The said material defining grooves may compriseat least two layers of material, in which case those layers preferablyhave different wetting properties. One of those layers, where present,preferably defines the lower portions of the walls of the groove and hassimilar wetting properties to the material that defines the base of thegroove (e.g. one of the electrodes).

To improve charge distribution and/or lower resistance in either or bothof the electrodes conductive material may be located in contact with theor each electrode. That conductive material preferably comprises a metalor an alloy. Where the device comprises the said insulating materialdefining grooves it is preferred that the said regions of conductivematerial at least partially overlap the insulating material. Preferablyat least one of the electrodes is patterned, most preferably linearlypatterned to leave a series of independent electrode strips, so as topermit independent control of each light-emissive region or each seriesof light-emissive regions. The said linear regions preferably correspondto rows of a display. In a preferred embodiment only one of theelectrodes is patterned to permit independent control of each series oflight-emissive regions and the other electrode is common to all thelight-emissive regions.

The device may include a structure for spatially narrowing the lightemission from at least one of the regions of light-emissive material.That structure may comprise some or all of the light-emissive structureof that region. Some non-limiting possibilities for such a structure arean interference, cavity and/or microcavity structure. Where thestructure includes a resonant cavity the cavity may be defined at leastin part by the light-emissive material and/or one or more electrodes. Aresonant structure may, in addition to or instead of spatially alteringthe emitted light, spectrally alter it for instance by spectrallyredistributing the light to influence the emission colour, e.g. topurify the colour and sharpen the emission spectrum.

The device may comprise an optical colour filter arranged for receivingand filtering light emitted from at least one or of the regions oflight-emissive material. All the light-emissive regions of a colour mayhave corresponding filters.

The light switching unit is suitably a liquid crystal unit. The array ofpixels may be an orthogonal array.

The organic light-emissive material is suitably a preferably solutionprocessable, and most preferably ink-jettable. The material is suitablya polymer and preferably a conjugated polymer.

The device may suitably also comprise a display control unit coupled tothe light switching unit and the backlight. The display control unit issuitably operable to address synchronously each region of organicmaterial together with the pixels of behind which that region lies. Thedisplay control unit is suitably capable of controlling the lightswitching unit and the backlight in response to video input signalsreceived by the display control unit.

Some preferred materials for components (where present) of thelight-emissive unit are as follows:

-   -   One of the electrodes or “charge carrier injecting layers” (the        hole injecting layer) preferably has a work function of greater        than 4.3 eV. That layer may comprise a metallic oxide such as        indium-tin oxide (“ITO”) or tin oxide (“TO”). The other        electrode/charge carrier injecting layer (the electron injecting        layer) preferably has a work function less than 3.5 eV. That        layer may suitably be made of a metal with a low work function        (Ca, Ba, Yb, Sm, Li etc.) or an alloy comprising one or more of        such metals together optionally with other metals (e.g. Al). At        least one of the electrode layers is suitably light        transmissive, and preferably transparent, suitably at the        frequency of light emission from one or more of the        light-emissive regions.    -   There may be one or more charge transport layers between the        light-emissive material and the charge carrier injecting layers.        The or each transport layer may suitably comprise one or more        polymers such as polystyrene sulphonic acid doped polyethylene        dioxythiophene (“PEDOT-PSS”) and/or        poly(2,7-(9,9di-n-octylfluorene)-(1,4-phenylene-(4-imino(benzoic        acid))-1,4-phenylene-(4-imino(benzoic acid))-1,4-phenylene))        (“BFA”) and/or polyaniline and/or PPV.    -   The or each organic light-emissive material may comprise one or        more individual organic materials, suitably polymers, preferably        conjugated or partially conjugated polymers. Suitable materials        include poly(pphenylenevinylene) (“PPY”),        poly(2-methoxy-5(2′-ethyl)hexyloxyphenylenevinylene)        (“MEH-PPV”), a PPV-derivative (e.g. a di-alkoxy or di-alkyl        derivative), a polyfluorene and/or a co-polymer incorporating        polyfluorene segments, PPVs and/or related co-polymers,        poly(2,7-(9,9-di-n-octylfluorene)(1,4-phenylene-((4-secbutylphenyl)imino)-1,4-phenylene))        (“TFB”),        poly(2,7(9,9-di-n-octylfluorene)(1,4-phenylene-((4-methylphenyl)imino)-1,4-phenylene-((4-methylphenyl)imino)-1,4-phenylene))        (“PFM”), poly(2,7-(9,9-di-n-octylfluorene) (“F8”) or        (2,7-(9,9-di-n-octylfluorene)-3,6-Benzothiadiazole) (“F8BT”).        Alternative materials include organic molecular light-emissive        materials, e.g. solution processible small molecule materials        such as spiro compounds (see EP 0 676 461 A), and other solution        processible small molecule or conjugated polymer        electroluminescent material as known in the prior art.

The present invention also provides a combination of a light-emissiveunit as described and a light switching unit as described.

It will be appreciated that the term ink-jet deposition refers to a typeof deposition process and does not imply that the material to bedeposited is an ink.

BRIEF DESCRIPTION OF DRAWINGS

The present invention will now be described by way of example withreference to the accompanying drawings, in which:

FIG. 1 shows a schematic cross-sectional view of a typical organiclight-emissive device (“OLED”);

FIG. 2 shows a schematic plan view of the basic structure of apassive-matrix LCD;

FIG. 3 shows a schematic plan view of part of a display device; and

FIG. 4 shows a schematic cross-sectional view of part of the displaydevice on the line A-A′ in FIG. 3.

DETAILED DESCRIPTION

The device of FIGS. 3 and 4 is a three-colour backlit LCD displaydevice. The device comprises a planar backlight unit 20 and a planar LCDunit 21. The backlight unit is located behind the LCD unit 21 in theviewing direction, so that in the emission direction light from thebacklight can pass through any light transmissive pixels of the LCD unitand towards a viewer 22 (FIG. 4).

The backlight is provided by an organic light-emissive device which hasa plurality of parallel linear regions 23-27 of light-emissive material.Each region is provided by one of three different emissive materialswhich emit correspondingly different colours of light. The materialsalternate so that the regions are in groups of red, green and blueemissive materials, as indicated in FIGS. 3 and 4 by the initials R, Gand B. The emissive regions are sandwiched between anode and cathodeelectrodes. The cathode electrode 29 is common to all the emissiveregions. The anode electrode is patterned into distinct rows 30-34 whicheach overlie a respective one of the emissive regions, so that theemissive regions can be controlled independently. The anode is formed ofa light transmissive material. The anode is deposited on a glasssubstrate 36.

The LCD unit is a normal passive-matrix LCD unit in which the pixels50-59 are arranged on an orthogonal grid and are connected by row 60-64and column 65, 66 electrodes.

The backlight is dimensioned and located relative to the LCD unit sothat each row of pixels in the LCD unit is underlain by one red, greenor blue emissive region of the backlight. In FIGS. 3 and 4 pixels 50 to54 are underlain by regions 23 to 27 respectively, as are pixels 55 to59 in FIG. 3 only.

The backlight unit and the LCD unit are connected to a control unit 45.The control unit receives a video data feed at 46, which defines thecolour pattern to be shown on the display. The video feed could comefrom any suitable source, such as (without limitation) a televisiondecoder, a personal computer or another electronic device. The patternmay represent a frame of a multi-frame moving image. In the normal way aseparating unit 47 of the control unit separates the colour pattern intored, green and blue pattern components which can be displayed in turn togive a user a time-averaged impression of the desired full colourpattern.

A driver unit 48 of the control unit then drives the pixels of the LCDdevice and, in synchronisation with the LCD device, the emissive regionsof the backlight. First, a suitable voltage and current is appliedbetween the cathode 29 and the anode electrode strip 30 whichcorresponds to red emissive region 23. This causes that regions to emitred light. At the same time the pixels 50, 55 of the LCD panel arecontrolled using electrodes 60, 65 and 66 to allow transmission onlywhere red light is to be emitted for the red component of the pattern.After a predetermined duration the driver unit turns off the redemissive region 23. Then a voltage and current to cause the greenemissive regions 24 to emit light and at the same time the pixels 51, 56of the LCD panel are controlled to allow transmission only where greenlight is to be emitted for the green component of the pattern. After apredetermined duration has passed the driver unit turns off the greenemissive region 24 and applies a voltage and current to cause the blueemissive region 25 to emit light at the same time as the pixels 52, 57of the LCD panel are controlled to allow transmission only where bluelight is to be emitted for the blue component of the pattern. The rapidswitching between colours gives a viewer an impression of a steadyfull-colour pattern. The process continues until all the rows of thedisplay have been scanned in this way. After that the display controllercauses the display to cycle through the rows again. To display a movingimage that next cycle could show the pattern of the next frame.

The device could use more or fewer than three emission colours, drivenin a corresponding way to that described above.

The duration of display of each colour could be the same or different.If the emissive regions for different colours differed in efficiencythen the duration of display could be related to the efficiency so thatthe time-averaged intensity of emission of each colour was substantiallythe same. The frequency of cycling through all three colours could vary;convenient frequencies are in the range from 50 to 120 Hz but higher orlower frequencies could be used.

The LCD device may have several thousand pixels. For instance, onetypical size is 800 columns by 600 rows, giving a total of 480,000pixels. A typical pixel size is 300×100 μm.

The light-emissive regions could run parallel to the rows or, lesspreferably, the columns of the LCD unit.

The manufacture of the device will now be described.

The backlight unit is manufactured taking as a first step a commerciallyavailable ITO-coated glass substrate. The ITO is then patterned in linesby a standard process such as photolithography to define the separateelectrode regions 30-34. Additional lines of metallisation could beprovided in contact with the ITO, e.g. between the ITO and the glasssubstrate, or in the plane of the ITO, to help distribute charge in theITO. Preferably the metallisation lines are at least in part locatedbetween the bank and the glass substrate.

Over the ITO an insulating layer shown generally at 49 is deposited andthen patterned to leave banks 70 of insulating material that lie betweenand overlap the edges of the anode strips 30-35. The banks 70 definegrooves in the gaps between adjacent banks. The banks may suitably beformed of polyimide or any other suitable insulating material such asSiO₂.

To help the formation of the light-emissive region in the groovesbetween the banks, especially when the material that is to form thelight-emissive region is deposited by ink-jet printing, a differentialwetting bank formation may be used. The bank may be formed from twolayers of material: one thin layer that is easily wettable by thematerial that is to form the light-emissive region, and over that athicker layer that defines the upper walls of the groove and is noteasily wettable by the material that is to form the light-emissiveregion. Then when the material that is to form the light-emissive regionis deposited in the region it tends to bead up at the base of thegroove.

The banks overlap the edges of the ITO anode strips. This helps todefine sharp edges to the light emission from the light-emissiveregions.

Then the light-emissive material is deposited by ink-jet printing intothe grooves that are defined between the banks. To deposit thelight-emitting material by inkjet printing the material or a precursorof the material is sprayed into the appropriate groove through anink-jet printer spray head. A suitable spraying cycle is 14,400 dropsper second, with a drop volume of 30 pl. The ink-jet system could be acontinuous stream system (e.g. using electrostatic directional controlof the stream) or a drop-on-demand system using e.g. a piezoelectric orbubble-jet print head. Some examples of suitable light-emissivematerials are: for the red emissive regions a di-alkoxy PPV, for thegreen emissive regions PPV (e.g. prepared by the precursor route) andfor the blue emissive regions a polyfluorene. Other materials and othercolours could, of course, be used. An alternative to using the groovesis to use a differential wetting process: the substrate on to which theemissive material is to be deposited could be treated with a wettingagent or a non-wetting agent to cause the ink-jetted material to bead upinto the desired formations over the anode strips.

Instead of ink-jet printing other selective deposition methods could beused, preferably methods that allow for easy patterning of thelight-emissive regions into stripes. Other selective deposition methodsthat may be suitable include screen printing (which is especiallyappropriate for large-area displays), masking techniques, off-setprinting, screen printing, electrostatic printing, gravure printing andflexographic printing.

Finally the cathode layer 29 is deposited over the banks and theemissive layers. PPV. The cathode layer could be a thin layer of calciumadjacent to the emissive regions, topped by a thicker layer ofaluminium.

One or more charge carrier transport layers, for instance of PEDOT-PSSor other materials could be located between the anode strips and thelight-emissive regions and/or between the cathode and the light-emissiveregions. These layers could help charge transport in the forwarddirection and/or help to block charge transport in the reversedirection. The same charge transport layer(s) could be used between therespective electrodes and all the emissive regions or specific chargetransport layers could be used for each emissive material. Especiallywhere the same material is used for the charge transport layer for allthe emissive regions it may be found that in many cases the device willperform acceptably if the charge transport layer is not patterned—thus acontinuous transport layer may be used over the entire device. Where acharge transport layer is to be patterned it may be deposited uniformlyand then patterned or may be deposited in a patterned form, e.g. byink-jet printing. Other layers could be present such as barrier layersto counteract degradation of the device during use, conducting layers toimprove charge distribution over the area of the device, insulatinglayers to inhibit unwanted charge migration, or protection layers toprevent degradation of parts of the device during manufacture.

Instead of (or in addition to) the patterning of the anode into linesthe cathode could be patterned into lines parallel to the rows ofemissive material. Where the “top” electrode (i.e. the later of theelectrodes to be deposited—the cathode in the example of FIGS. 3 and 4)is patterned it will be appreciated that the banks 70 can usefully serveto protect lower layers from damage from the process of patterning thetop electrode, particularly by spacing active pixel edges laterally fromthe patterned edges of the top electrode regions.

The cathode could be located in front of the emissive regions, with theanode behind them. In that case, the cathode should be of a lighttransmissive material.

It may be desirable to sharpen spatially the emission from one or moreof the emissive regions to improve the effect of the display. Oneefficient way to achieve this is by defining a resonant cavity withinthe device which can spatially and/or spectrally narrow the emission bymeans of interference and/or cavity effects. One particularly efficientway of implementing such a cavity is by integrating the emissivematerial itself into such a cavity, with (for instance) the spacingbetween the anode and cathode electrodes on either side of the emissivematerial defining the ends of the cavity. Additional layers such asdielectric stacks could be provided to define some or all of the cavity.The cavity itself could be augmented by the thickness of the organiclayers.

The LCD unit is a conventional passive matrix LCD unit. Any suitabletype of LCD unit could be used, including ferroelectric, TN and STNtypes. It will be appreciated that liquid crystal displays are just oneclass of light-switching devices that could be used in relation to thepresent invention and that other suitable devices could be used instead.

The present invention may include any feature or combination of featuresdisclosed herein either implicitly or explicitly or any generalisationthereof, irrespective of whether it relates to the presently claimedinvention. In view of the foregoing description it will be evident to aperson skilled in the art that various modifications may be made withinthe scope of the invention.

1-28. (canceled)
 29. A display device comprising: a first electrode; asmall molecule organic light emissive layer deposited over the firstelectrode, wherein the small molecule organic light emissive layer is apatterned layer which has been deposited by solution processing; and asecond electrode deposited over the organic light emissive layer. 30.The display device of claim 29, wherein the organic light emissive layerhas been deposited by a process of ink-jet deposition.
 31. The displaydevice of claim 29, wherein the organic light emissive patterned layercomprises regions of red, green and blue light emissive materials. 32.The display device of claim 29 including: a charge transport layerbetween the organic light emissive layer and the first electrode; andthe organic light emissive layer is disposed over and in physicalcontact with the charge transport layer.
 33. The display device of claim32, wherein the charge transport layer comprises one or more polymers.34. The display device of claim 33, wherein the one or more polymerscomprise polystyrene sulphonic acid doped polyethylene dioxythiophene(PDOT:PSS) and/orpoly(2,7-(9,9-di-n-octylfluorene)-(1,4-phenylene-(4-imino(benzoicacid))-1,4-phenylene-(4-imino(benzoic acid))-1,4-phenylene))(BFA) and/orpolyaniline and/or PPV.
 35. The display device of claim 32, wherein thecharge transport layer is patterned.
 36. The display device of claim 35,wherein the charge transport layer has been deposited by a process ofink-jet deposition.